Structure, Fluctuation, and Relaxation in Solutions

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Source: The Journal of physical chemistry v. The spectra have been evaluated in terms of suitable relaxation functions. In addition to a frequency-independent asymptotic high-frequency term, all spectra reveal a critical term and a Debye-type relaxation term with relaxation time around 0. The former is evaluated in the light of the Bhattacharjee—Ferrell dynamic scaling theory.

It is assigned to the critical domain structure fluctuations of the membranes.

Rate exchange rather than relaxation controls structural recovery

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Thermodynamic Theory Of Structure, Stability and Fluctuation Russian

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Please enable JavaScript to access the full features of the site or access our non-JavaScript page. Volume , Previous Article Next Article. From the journal: Faraday Discussions. Ordering and dynamics of soft spheres in melt and solution. You have access to this article. Please wait while we load your content Alekhin, and O. Bilous, Acoustic properties of liquid systems near the critical temperature, Ukr.

NMR Methods to Study Dynamic Allostery

Ferrell, Decoupled-mode dynamical scaling theory of the binary-liquid phase transition, Phys. Kawasaki, Kinetic equations and time correlation functions of critical fluctuations, Ann. Alekhin and O. Bilous, The phenomenological approach to estimating critical indices of critical fluid, High Temp. Bhattacharjee and R.

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Ferrell, Dynamic scaling theory for the critical ultrasonic attenuation in a binary liquid, Phys. A 24, [DOI: Bhattacharjee, S. Mirzaev, and U. Kaatze, Does the viscosity exponent derive from ultrasonic attenuation spectra? Schrader, and U. Kaatze, Zwitterion headgroup orientation correlation and mobility and the domain structure of membranes, J. B , [DOI: Folk and G. Moser, Frequency-dependent shear viscosity, sound velocity, and sound attenuation near the critical point in liquids.

Comparison with experiment, Phys.

E 57, [DOI: Onuki, Bulk viscosity near the critical point, J. Bogolyubov Institute for Theoretical Physics. Skip to main content Skip to main navigation menu Skip to site footer. Keywords: ultrasound velocity, ultrasound absorption, critical stratification point, binary solution, concentration fluctuations, relaxation time.

Abstract The propagation velocity and the absorption coefficient of ultrasound in a frequency range of 5— MHz in a n-pentanol—nitromethane solution in a vicinity of its critical stratification point from the homogeneous state side have been studied. References A.

Structure, Fluctuation, and Relaxation in Solutions

Press, Cambridge, Bulavin, O. Vasylkevych et al. How to Cite. Bulavin, L. Ukrainian Journal of Physics , 61 10 ,

Structure and Forces in Shear Jammed Sphere Packings by Srikanth Sastry